Rare Earths and the Balance Problem: How to Deal with Changing Markets?

The balance between the market demand and the natural abundance of the rare-earth elements (REEs) in ores, often referred to as the Balance Problem (or the Balancing Problem), is a major issue for REE suppliers. The ideal situation is a perfect match between the market demand for and the production of REEs, so that there are no surpluses of any of the REEs. This means that the rare-earth industry must find new uses for REEs that are available in excess and search for substitutes for REEs that have either limited availability or are high in demand. We present an overview of the trends in the applications for the different REEs and show that the demand for REEs for use in magnets, catalysts, and alloys is still increasing, while the application of REEs in polishing agents, glass, and ceramics are stable. On the other hand, the use of REEs in nickel–metal-hydride (NiMH) batteries and lamp phosphors is decreasing. These changes in the REE market have an influence on the Balance Problem, because the REEs that can be recycled from fluorescent lamps, cathode-ray tubes (CRTs), and NiMH batteries have to be at least partly reused in other applications. Magnesium and aluminum alloys offer an opportunity to mitigate the Balance Problem caused by these changes in the REE market. This is illustrated for REEs that can be recycled from fluorescent-lamp phosphor waste, CRT phosphors, and NiMH batteries. At present, five REEs (Nd, Eu, Tb, Dy, and Y) are being considered as very critical by Europe, the United States, and Japan, but we forecast that in the medium term, only neodymium will remain a critical REE. This paper discusses the relationship between criticality and the Balance Problem and shows how this relationship influences the market for specific REEs.This work has received funding from the European Union’s Horizon 2020 research and innovation programme under Grant Agreement No 680629 (REMAGHIC: New Recovery Processes to produce Rare Earth-Magnesium Alloys of High Performance and Low Cost) (project website: http://www.remaghic-project. eu). KB and PTJ acknowledge funding from the European Community’s Seventh Framework Programme ([FP7/2007–2013]) under Grant Agreement No. 607411 (MC-ITN EREAN: European Rare Earth Magnet Recycling Network) (project website of EREAN: http:// www.erean.eu). Paul McGuiness (Sciencewriter.si, Slovenia) is acknowledged for the drawing of the figures

Towards a hydrogeomorphological understanding of proglacial catchments: an assessment of groundwater storage and release in an Alpine catchment

Proglacial margins form when glaciers retreat and create zones with distinctive ecological, geomorphological and hydrological properties in Alpine environments. There is extensive literature on the geomorphology and sediment transport in such areas as well as on glacial hydrology, but there is much less research into the specific hydrological behavior of the landforms that develop after glacier retreat in and close to proglacial margins. Recent reviews have highlighted the presence of groundwater stores even in such rapidly draining environments. Here, we describe the hydrological functioning of different superficial landforms within and around the proglacial margin of the Otemma glacier, a temperate Alpine glacier in the Swiss Alps; we characterize the timing and amount of the transmission of different water sources (rain, snowmelt, ice melt) to the landforms and between them, and we compare the relationship between these processes and the catchment-scale discharge. The latter is based upon a recession-analysis-based framework. In quantifying the relative groundwater storage volumes of different superficial landforms, we show that steep zones only store water on the timescale of days, while flatter areas maintain baseflow on the order of several weeks. These landforms themselves fail to explain the catchment-scale recession patterns; our results point towards the presence of an unidentified storage compartment on the order of 40 mm, which releases water during the cold months. We suggest attributing this missing storage to deeper bedrock flowpaths. Finally, the key insights gained here into the interplay of different landforms as well as the proposed analysis framework are readily transferable to other similar proglacial margins and should contribute to a better understanding of the future hydrogeological behavior of such catchments.</p

Optimization of drip irrigation using a sensor network in Sahel Region (Burkina Faso) - Analysis of soil water and plant dynamics in the framework of project Info4Dourou 2.0

The research project Info4Dourou 2.0 's main goal is to improve agriculture in semi-arid regions by developing a support system that optimizes agricultural production and water consumption based on continuous soil humidity measurements using a sensor network. In this context, the main purpose of the study was to give more scientific support to the agronomic model on which the sensor network is based. In particular the research aims at understanding the soil water and plant dynamics in order to give recommendations on the system design. The main feature of the system is to indicate when irrigation must be triggered and in which soil moisture conditions. The thesis developed a numerical model based on the software HYDRUS 2D to acquire a precise knowledge on the soil water dynamics and was calibrated and coupled with field experiments on two vegetable crops of eggplant and cabbage in Burkina Faso using drip kit irrigation systems. A great focus was given on the plant response to different irrigation schedules and to water stress, considering aerial biomass development, root distribution and final yields. Water stress was linked to continuous measurements of the soil matrix potential at different depth and locations. The field experiments showed that a daily irrigation frequency resulted to better canopy development during the first part of the growth but that great water savings are possible by optimizing the schedule. Water stress was difficult to track precisely by following daily sap flow behaviour which suggested that plant stress occurs before transpiration reduction, especially when biomass is building up. The adaptability of the root distribution was demonstrated and was clearly correlated with the wetted zone which depended on the irrigation schedule. From the numerical model, it was shown that using one sensor at a depth of about 10 cm was most appropriate in order to pilot irrigation during the whole crop growth. The analysis showed that most of the water savings could be achieved at relatively high threshold values and that low thresholds mainly resulted to transpiration reduction which was not advisable. A threshold of -20 kPa was proposed for the beginning of the growth stage which then decreases to a value of -50 kPa at full canopy development. These thresholds are believed to be adequate for most vegetable crops since they allow keeping the soil matrix potential in the root zone at values that are tolerated by most plants. An analysis of the influence of the soil texture also showed that similar values seem to perform well for most soils, if assuming an adaptation of the root distribution to the wetted zone. The study focused mainly on water stress but more research could be done on the impact of the irrigation system on nutrients availability for example

Coseismic drop of seismic velocity caused by the 2023 Turkey–Syria earthquakes

The Mw 7.8 earthquake in Turkey on 6 February 2023 was extraordinary for various reasons. It originated in depth of only 10 km, ruptured along a fault plane around 300 km long and the surface was covered by an extensive network of high-quality seismic instruments. The strong motions resulted in a vast number of tragic casualties and huge material losses in Turkey and Syria. However, abundant and proximate seismic observations of this event and numerous aftershocks give an opportunity to deepen the understanding of earthquake processes. In this study, we carried out an assessment of coseismic changes of seismic velocity using Passive Image Interferometry. We used data from one strong-motion and twenty-four broadband sensors. We observed coseismic drops of seismic velocity, which reached up to -1.79 per cent at a location directly at the ruptured East Anatolian Fault Zone. Along the Mw 7.8 earthquake fault, we observe frequency dependence of the velocity changes. At frequencies above 0.5 Hz, the velocity drops seem to be higher at locations close to the ruptured faults than in the more distant areas

Photostabilisation of an omniphobic, drop-castable surface coating by transformation of a self-assembled supramolecular xerogel into a covalent polymer xerogel

Simple drop-casting of a new gelator, incorporating a diacetylene core and fluorous ponytails, yields porous xerogels as surface coatings. The mechanical stability of such coatings is quantified with a self-devised scratch balance, introducing a simple and universal quantification method to compare the stability of μm-scale coatings. The diameters of the pores in the coatings can be controlled by the breath figure effect. The coatings display omniphobicity with static contact angles of up to 139° (water) and 96° (n-decane). The coatings are topochemically polymerised by UV irradiation, enhancing the mechanical stability by up to four times. Simultaneously, the water and n-decane contact angles are increased by about 9° and 4° respectively due to a slight increase in surface roughness